When using copper pyrophosphate brightener, how can one identify the fault problems through the Hall cell test?

2026-05-22 16:48:27

Some electroplating factories have reported that when using copper pyrophosphate brightener to plate the samples, if the test pieces are observed under a 30x magnifying glass, there is a phenomenon of poor flatness. What is the cause of this? First of all, we need to know that there are multiple symptoms for the unevenness of the coating, and the causes corresponding to different symptoms are also different. Next, let's carefully analyze this so that we can make full use of the opportunity when troubleshooting.

① There are fine granular pinholes

Possible reasons include:

1. The pH value of the plating solution is too high

2. Decrease in cathode current efficiency

3. During the application of copper brightener based on copper pyrophosphate, due to the high viscosity of the copper plating solution made from copper pyrophosphate, the solution has poor wetting property, and fine hydrogen bubbles remain and form gas pores

4. Due to the presence of oil stains in the pre-plating solution, the pre-cleaning water, and the plating solution, and their attachment to the workpiece surface in the form of fine dots, insulating small points are formed, resulting in plating layer pinholes

② There are raised sediment deposits, indicating poor leveling

Possible reasons include:

1. If the pH value is too low or too high, the coordination strength is inappropriate

2. The bath solution is too dilute, and the concentration of the main salt is accordingly too low

3. Insufficient brightener for blister copper

4. Poor pre-polishing of the substrate before plating

5. Uneven pre-coating layer

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Guangdong Bigely Technology Co., Ltd. ,founded in 2003, is a high-tech enterprise integrating R & D,production, sales and service, specializing in the production of electroplating additives. As a famous electroplating additives source manufacturer in China, Bigely has over 20 years' experience in electroplating additives production and own production base of 5000 square meters. We can produce 15,000 tons of electroplating additives every year, which can fully meet the needs of customers.

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